2134/15946
Allen T. Ekubo
Allen T.
Ekubo
Mark Elsegood
Mark
Elsegood
Andrew Lake
Andrew
Lake
Martin Smith
Martin
Smith
Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts
Loughborough University
2014
untagged
Chemical Sciences not elsewhere classified
Inorganic Chemistry
2014-09-26 14:12:16
Journal contribution
https://repository.lboro.ac.uk/articles/journal_contribution/Unusual_metal-coordinated_zwitterionic_P-C-N-C-N-C_phosphido_adducts/9393929
Rare examples of homodinuclear zwitterionic PdII and PtII complexes
with bridging, two-coordinate P{cyclo-CH2N(R)CHN-
(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been
characterized by single-crystal X-ray diffraction using synchrotron
radiation. Short N-C distances and enlarged N-C-N bond
angles support electron delocalization in the central N-C-N
backbone.