2134/13967
Benjamin Buckley
Benjamin
Buckley
Sandie Dann
Sandie
Dann
Daniel P. Harris
Daniel P.
Harris
Harry Heaney
Harry
Heaney
Emma C. Stubbs
Emma C.
Stubbs
Alkynylcopper(I) polymers and their use in a mechanistic study of alkyne-azide click reactions
Loughborough University
2014
untagged
Chemical Sciences not elsewhere classified
2014-01-14 15:14:17
Journal contribution
https://repository.lboro.ac.uk/articles/journal_contribution/Alkynylcopper_I_polymers_and_their_use_in_a_mechanistic_study_of_alkyne-azide_click_reactions/9395279
Polymeric dinuclear alkynylcopper(I) complexes, for example phenylethynylcopper(I), can be prepared by a robust method involving the interaction of terminal alkynes with copper(II) salts in acetonitrile. The use of the ladder polymers provides heterogeneous catalysts for copper-catalyzed azide–alkyne cycloaddition (CuAAC) reactions and provides important mechanistic information.