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Alkynylcopper(I) polymers and their use in a mechanistic study of alkyne-azide click reactions

journal contribution
posted on 2014-01-14, 15:14 authored by Benjamin BuckleyBenjamin Buckley, Sandie DannSandie Dann, Daniel P. Harris, Harry Heaney, Emma C. Stubbs
Polymeric dinuclear alkynylcopper(I) complexes, for example phenylethynylcopper(I), can be prepared by a robust method involving the interaction of terminal alkynes with copper(II) salts in acetonitrile. The use of the ladder polymers provides heterogeneous catalysts for copper-catalyzed azide–alkyne cycloaddition (CuAAC) reactions and provides important mechanistic information.

History

School

  • Science

Department

  • Chemistry

Citation

BUCKLEY, B.R. ... et al, 2010. Alkynylcopper(I) polymers and their use in a mechanistic study of alkyne-azide click reactions. Chemical Communications, 46 (13), pp. 2274 - 2276

Publisher

© Royal Society of Chemistry

Version

  • VoR (Version of Record)

Publication date

2010

Notes

This article is closed access, it was published in the journal Chemical Communications [© Royal Society of Chemistry]. The definitive version is available at: http://dx.doi.org/10.1039/b924649e

ISSN

1359-7345

Language

  • en

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