An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts

Hill, Anthony W.; Elsegood, Mark; Kimber, Marc

JOC Manuscript Lupin.pdf (315.79 kB)

An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts

journal contribution

posted on 2014-01-10, 13:15 authored by Anthony W. Hill, Mark ElsegoodMark Elsegood, Marc KimberMarc Kimber

An intermolecular hydroamination of allenamides with arylamines has been achieved under mild Au(I) catalysis conditions delivering allylamino E-enamides stereoselectively and in high yield. The reaction is made possible via a convenient method for conjugated N-acyliminium formation.

History

School

Science

Department

Chemistry

Citation

HILL, A.W., ELSEGOOD, M.R.J. and KIMBER, M.C., 2010. An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts. Journal of Organic Chemistry, 75 (15), pp. 5406 - 5409

Publisher

Version

AM (Accepted Manuscript)

Publication date

2010

Notes

This article was published in the serial Journal of Organic Chemistry [© American Chemical Society]. The definitive version is available at: http://dx.doi.org/10.1021/jo101035n