Boroxine Letter revised.pdf (560.51 kB)
Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base
journal contribution
posted on 2015-03-02, 15:39 authored by Mark ElsegoodMark Elsegood, Marc KimberMarc KimberPyridyl-assisted templating of phenyl boronic acid has been utilised to link two remote boroxines via a chiral spacer. The chiral spacer is a carbocyclic analogue of Tröger's base and contains a unique chiral cavity, and the flanking boroxine units have been shown, by single crystal X-ray analysis, to extend the size and shape of this cavity.
History
School
- Science
Department
- Chemistry
Published in
Tetrahedron LettersVolume
56Issue
2Pages
346 - 349Citation
ELSEGOOD, M.R.J. and KIMBER, M.C., 2015. Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base. Tetrahedron Letters, 56 (2), pp. 346 - 349Publisher
© Elsevier LtdVersion
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2015Notes
NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 56, issue 2, January 2015, DOI:10.1016/j.tetlet.2014.11.094ISSN
0040-4039eISSN
1873-3581Publisher version
Language
- en
