This study examines the impact of doping on the resistivity of sputtered cupric oxide (CuO), and investigates the effects of co-sputtering CuO with tin dioxide (SnO2). It was found that films sputtered from a 2 at. % sodium-doped target have resistivities of four orders of magnitude lower than equivalent undoped films. Addition of oxygen was found to reduce the resistivity further. The best films were found to have resistivities of 4.3x10-2 Ω.cm. Co-sputtering with SnO2 was found to increase the band gap significantly, although it also caused an increase in the resistivity. All mixed oxide films were both amorphous and p-type.
Funding
The authors would like to acknowledge funding for the work through the EPSRC Supergen Supersolar Hub.
History
School
Mechanical, Electrical and Manufacturing Engineering
Published in
Energy Procedia
Volume
60
Pages
129 - 134
Citation
ISHERWOOD, P.J.M. and WALLS, M., 2014. Cupric oxide-based p-type transparent conductors. Energy Procedia, 60, pp.129-134.
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 Unported (CC BY-NC-ND 3.0) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/3.0/
Publication date
2014
Notes
This is an Open Access Article. It is published by Elsevier under the Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported Licence (CC BY-NC-ND 3.0). Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/3.0/. This paper was also presented at the E-MRS Spring Meeting 2014 Symposium Y “Advanced materials and characterization techniques
for solar cells II”, 26-30 May 2014, Lille, France.