jo2c03002_si_001.pdf (2.99 MB)
Supplementary information files for A family of bis-naphthyl C2-symmetric and asymmetric clefts: Synthesis, solid state structure and calculation of the interplanar angle
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posted on 2023-03-09, 16:15 authored by Gazalah Elgadi, Mark ElsegoodMark Elsegood, Miheal Patel, Paulo A Netz, Tiago E de Oliveira, Marc KimberMarc KimberSupplementary files for article A family of bis-naphthyl C2-symmetric and asymmetric clefts: Synthesis, solid state structure and calculation of the interplanar angle
The synthesis of a new family of naphthalenoid C2-symmetric clefts has been realized through a four-step synthetic sequence giving three C2-symmetric clefts and a rare nonsymmetric example. Subsequently, stereoselective reduction of the carbonyl groups at C-8 and C-16 then provides cleft molecules with hydrogen bonding potential. Using single-crystal X-ray and computational analysis, the cleft angle of the dione has been determined.
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