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Supplementary information files for Monofunctionalized fluorinated bambusurils and their conjugates for anion transport and extraction

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posted on 2023-03-02, 15:01 authored by Nicola Alessandro De Simone, Matúš Chvojka, Jana Lapešováář, Luis Martínez-Crespo, Petr Slávik, Jan Sokolov, Stephen ButlerStephen Butler, Hennie Valkenier, Vladimír Šindelář

Supplemental files for article Monofunctionalized fluorinated bambusurils and their conjugates for anion transport and extraction


Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid-liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers. 

Funding

Monofunctionalized bambusurils and their supramolecular properties

Czech Science Foundation

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RECETOX Research Infrastructure (No. LM2018121)

CETOCOEN Excellence

European Commission

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Transport of phosphorylated compounds across lipid bilayers by supramolecular receptors

European Research Council

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Czech Infrastructure for Integrative Structural Biology

Ministry of Education Youth and Sports

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FNRS for Aspirant fellowship funding (40006851)

Luminescent Host Molecules for Multisite Recognition of Polyphosphate Anions

Engineering and Physical Sciences Research Council

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