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Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes

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posted on 20.07.2015 by Philip C. Bulman Page, Yohan Chan, John Liddle, Mark Elsegood
A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product epoxides.

Funding

This work was supported by Loughborough University, the Engineering and Physical Sciences Research Council, GlaxoSmithKline (CASE award), and The Royal Society (P.C.B.P.: Industry Fellowship).

History

School

  • Science

Department

  • Chemistry

Published in

TETRAHEDRON

Volume

70

Issue

40

Pages

7283 - 7305 (23)

Citation

PAGE, P.C.B. ... et al, 2014. Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes. Tetraheddron, 70 (40), pp.7283-7305

Publisher

© Elsevier

Version

VoR (Version of Record)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution 4.0 International (CC BY 4.0) licence. Full details of this licence are available at: http://creativecommons.org/licenses/ by/4.0/

Publication date

2014

Notes

This is an Open Access Article. It is published by Elsevier as Open Access at: http://dx.doi.org/10.1016/j.tet.2014.07.052

ISSN

0040-4020

Language

en

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