Kinetic resolution in asymmetric epoxidation using iminium salt catalysis.pdf (656.35 kB)

Kinetic resolution in asymmetric epoxidation using iminium salt catalysis

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journal contribution
posted on 25.02.2015, 11:36 by Philip C. Bulman Page, Louise F. Appleby, Yohan Chan, David P. Day, Benjamin Buckley, Alexandra M.Z. Slawin, Steven M. Allin, Michael J. McKenzie
The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.

Funding

This investigation has enjoyed the support of the EPSRC, the University of East Anglia, Charnwood Molecular Ltd, and the ERDF (IS:CE-Chem & INTERREG IVa Programme 4061). We acknowledge the support of The Royal Society (PCBP: Industry Fellowship). We are also indebted to the EPSRC Mass Spectrometry Unit, Swansea.

History

School

  • Science

Department

  • Chemistry

Published in

JOURNAL OF ORGANIC CHEMISTRY

Volume

78

Issue

16

Pages

8074 - 8082 (9)

Citation

PAGE, P.C.B. ... et al., 2013. Kinetic resolution in asymmetric epoxidation using iminium salt catalysis. Journal of Organic Chemistry, 78 (16), pp. 8074 - 8082.

Publisher

American Chemical Society

Version

VoR (Version of Record)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution 4.0 International (CC BY 4.0) licence. Full details of this licence are available at: http://creativecommons.org/licenses/ by/4.0/

Publication date

2013

Notes

This is an Open Access Article. It is published by the American Chemical Society under the Creative Commons Attribution 4.0 Unported Licence (CC BY). Full details of this licence are available at: http://creativecommons.org/licenses/by/4.0/

ISSN

0022-3263

Language

en

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