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Measuring spin ... spin interactions between heterospins in a hybrid [2]rotaxane

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posted on 28.03.2019 by Marie-Emmanuelle Boulon, Antonio Fernandez-Mato, Eufemio Pineda, Nicholas F. Chilton, Grigore Timco, Alistair J. Fielding, Richard E. Winpenny
Use of molecular electron spins as qubits for quantum computing will depend on the ability to produce molecules with weak but measurable interactions between the qubits. Here we demonstrate use of pulsed EPR spectroscopy to measure the interaction between two inequivalent spins in a hybrid rotaxane molecule.

Funding

We thank the EPSRC(UK) for funding post‐doctoral positions (M.‐E.B. and A.F., grant EP/L018470/1) and for an X‐ray diffractometer (EP/K039547/1) as well as for the EPSRC National Electron Paramagnetic Resonance Facility and Service. N.F.C. thanks the Ramsay Memorial Trust for a Research Fellowship.

History

School

  • Science

Department

  • Chemistry

Published in

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Volume

56

Issue

14

Pages

3876 - 3879

Citation

BOULON, M-E. ... et al, 2017. Measuring spin ... spin interactions between heterospins in a hybrid [2]rotaxane. Angewandte Chemie International Edition, 56 (14), pp.3876-3879.

Publisher

Wiley © The Authors

Version

VoR (Version of Record)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution 4.0 International (CC BY 4.0) licence. Full details of this licence are available at: http://creativecommons.org/licenses/ by/4.0/

Publication date

2017-03-09

Notes

This is an Open Access article. It is published by Wiley under the Creative Commons Attribution 4.0 International Licence (CC BY). Full details of this licence are available at: https://creativecommons.org/licenses/by/4.0/

ISSN

1433-7851

eISSN

1521-3773

Language

en

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