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New polyaza tris-ferrocene and tris-2,2′-bipyridyl macrobicyclic cryptand molecules. Isolation of homo- and hetero-polymetallic zinc(II) and copper(I) cryptates containing externally coordinated ruthenium(III) cations
journal contributionposted on 17.01.2013 by Paul D. Beer, Oldrich Kocian, Roger J. Mortimer, Paul Spencer
Any type of content formally published in an academic journal, usually following a peer-review process.
New multisite ligands containing either three peripherally linked ferrocene redox centres (L1,L3) or three externally orientated 2,2′-bipyridyl transition metal recognition sites (L2,L4) have been prepared and their homo- and hetero-polymetallic zinc(II) and copper(I) cryptates incorporating in the case of L2 and L4 externally coordinated ruthenium(II) cations have been isolated.