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Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

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journal contribution
posted on 19.09.2006, 16:58 by Philip C. Bulman Page, Benjamin Buckley, David Barros, A. John Blacker, Harry Heaney, Brian A. Marples
A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium mono-peroxysulfate (TPPP) as oxidant, giving ees of up to 97%.

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  • Science

Department

  • Chemistry

Pages

322791 bytes

Citation

PAGE et al, 2006. Non-aqueous iminium salt mediated catalytic asymmetric epoxidation. Tetrahedron 62 (28), pp. 6607-6613

Publisher

© Elsevier

Publication date

2006

Notes

This article was published in the journal, Tetrahedron [© Elsevier] and is also available at http://www.sciencedirect.com/science/journal/00404020

ISSN

0040-4020

Language

en

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