JSSE 16 (2012) 3723-3724 pre-print.pdf (124.35 kB)
0/0

Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate

Download (124.35 kB)
journal contribution
posted on 10.01.2013 by Ray Barton, Hassan Kellawi, Frank Marken, Roger J. Mortimer, David R. Rosseinsky
Prussian-blue (PB) film for electro-chromism can be electro-deposited on to an electrode (usually tin-doped indium oxide/glass) either directly from a PB colloid or from ferric ferricyanide in a two-electrode electro-chemical cell by applying a reductive potential. Alternatively, a “sacrificial” electron-producing silver flag electrode in the solution, when connected to the PB-receiving electrode, can effect the required reductive deposition. A silver spot, here innovatively applied as silver paint directly onto the deposition electrode, produces PB film on immersion in the iron(III)(III) solution, obviating the separate counter-electrode method.

History

School

  • Science

Department

  • Chemistry

Citation

BARTON, R.T. ... et al., 2012. Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate. Journal of Solid State Electrochemistry, 16 (12), pp. 3723 - 3724.

Publisher

© Springer-Verlag

Version

AM (Accepted Manuscript)

Publication date

2012

Notes

This article was published in the Journal of Solid State Electrochemistry [© Springer-Verlag] and the definitive version is available at: http://dx.doi.org/10.1007/s10008-012-1811-7

ISSN

1432-8488

eISSN

1433-0768

Language

en

Exports

Logo branding

Exports