File(s) not publicly available

Reason: This item is currently closed access.

The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis

journal contribution
posted on 28.10.2009 by Benjamin Buckley, Stephen P. Neary
We herein report a highly active catalyst system using for the first time a thiadiazolidine 1-oxide as a ligand for palladium in the Mizoroki–Heck reaction. Excellent yields of stilbenes derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol% catalyst. The ligand/palladium system can be stored as a stock solution open to air at room temperature with no observable loss of activity for a period of several weeks/months.

History

School

  • Science

Department

  • Chemistry

Citation

BUCKLEY, B.R. and NEARY, S.P., 2009. The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis. Advanced Synthesis & Catalysis, 351 (1), pp. 71-77.

Publisher

© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Version

NA (Not Applicable or Unknown)

Publication date

2009

Notes

This article is closed access. It was published in the journal, Advanced Synthesis & Catalysis [© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim] at: http://dx.doi.org/10.1002/adsc.200800522

ISSN

1615-4150;1615-4169

Language

en

Exports