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Thiadiazolidine 1-oxide systems for phosphine-free palladium-mediated catalysis

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journal contribution
posted on 10.01.2014, 12:12 by Benjamin Buckley, Stephen P. Neary
We herein report several highly active catalyst systems with thiadiazolidine 1-oxides as ligands for palladium in the Mizoroki–Heck reaction. Excellent yields of stilbenes derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol % catalyst. The ligand/palladium system can be stored as a stock solution open to air at room temperature with no observable loss of activity for a period of several months.

History

School

  • Science

Department

  • Chemistry

Citation

BUCKLEY, B.R. and NEARY, S.P., 2010. Thiadiazolidine 1-oxide systems for phosphine-free palladium-mediated catalysis. Tetrahedron, 66 (40), pp. 7988 - 7994.

Publisher

© Elsevier Ltd.

Version

AM (Accepted Manuscript)

Publication date

2010

Notes

This article was published in the journal, Tetrahedron [© Elsevier Ltd.] and the definitive version is available at: http://dx.doi.org/10.1016/j.tet.2010.08.018

ISSN

0040-4020

Language

en

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