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Towards a total synthesis of the manadomanzamine alkaloids: the first asymmetric construction of the pentacyclic indole core

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posted on 26.06.2007 by Steven Allin, Liam J. Duffy, Philip C. Bulman Page, Vickie McKee, Michael J. McKenzie
We report a highly diastereoselective approach for the synthesis of the pentacyclic indole core of the manadomanzamine alkaloid skeleton, with complete control over the relative and absolute stereochemistries at the three contiguous stereocentres at ring positions 1, 10, and 24, from a readily available chiral template.

History

School

  • Science

Department

  • Chemistry

Citation

ALLIN, S.M. et al, 2007. Towards a total synthesis of the manadomanzamine alkaloids: the first asymmetric construction of the pentacyclic indole core. Tetrahedron Letters, 48(27), pp. 4711-4714

Publisher

© Elsevier

Publication date

2007

Notes

This article was published in the journal, Tetrahedron Letters [© Elsevier]. The definitive version is available at: http://www.sciencedirect.com/science/journal/00404039.

ISSN

0040-4039

Language

en

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