"Hydrothermal wrapping" with poly(4-vinylpyridine) introduces functionality: pH-sensitive core-shell carbon nanomaterials
journal contributionposted on 26.09.2014 by Katherine Lawrence, Geoffrey W. Nelson, John S. Foord, Monica Felipe-Sotelo, Nick Evans, John M. Mitchels, Tony D. James, Fengjie Xia, Frank Marken
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Negatively charged carbon nanoparticles (surface-phenylsulfonated) are “wrapped” in a poly(4-vinylpyridine) cationomer and hydrothermally converted into a pH-responsive core–shell nano-composite. With a “thin shell” this nano-material (ca. 20–40 nm diameter) is water-insoluble but readily dispersed into ethanol and deposited onto electrodes. Zeta-potential measurements suggest a point of zero charge (PZC) at ca. pH 4.5 with negative functional groups dominating in the more alkaline range and positive functional groups dominating in the acidic range. XPS data suggest carboxylate and pyridinium-like functional groups. This is further confirmed in voltammetric measurements for adsorbed cations (methylene blue) and adsorbed anions (indigo carmine). The specific capacitance reaches a maximum of 13 F g−1 at the PZC explained here tentatively by a “shell charging” effect within the nanoparticle shell.
K.L. thanks the EPSRC for a DTA studentship to fund this research. This work was also supported by the CSC (China Scholarship Council, file number 2010695033) for F.X.