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Download fileA complementary approach to conjugated Ν-acyliminium formation through photoredox-catalyzed intermolecular radical addition to allenamides and allencarbamates
journal contribution
posted on 2021-03-22, 11:45 authored by Olusesan K Koleoso, Matthew TurnerMatthew Turner, Felix PlasserFelix Plasser, Marc KimberMarc KimberAn intermolecular radical addition, using photoredox catalysis, to allenamides and allencarbamates is reported. This transformation synthesizes N-acyl-N’-aryl-N,N’-allylaminals, and proceeds by a conjugated N-acyliminium intermediate that previously has principally been generated by electrophilic activation methods. The radical adds to the central carbon of the allene giving a conjugated N-acyliminium that undergoes nucleophilic addition by arylamines and alcohols.
Funding
Loughborough University and the Tertiary Education Trust Fund (TETFund) Abuja, Nigeria (O.K.K.).
History
School
- Science
Department
- Chemistry
Published in
Beilstein Journal of Organic ChemistryVolume
16Pages
1983 - 1990Publisher
Beilstein InstitutVersion
- VoR (Version of Record)
Rights holder
© The authorsPublisher statement
This is an Open Access Article. It is published by Beilstein Institut under the Creative Commons Attribution 4.0 Unported Licence (CC BY). Full details of this licence are available at: http://creativecommons.org/licenses/by/4.0/Acceptance date
2020-08-05Publication date
2020-08-12Copyright date
2020ISSN
1860-5397eISSN
1860-5397Publisher version
Language
- en