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A numerical study of structural change and anisotropic permeability in compressed carbon cloth polymer electrolyte fuel cell gas diffusion layers

journal contribution
posted on 02.10.2012, 15:36 by Pratap Rama, Yu Liu, Rui ChenRui Chen, Hossein Ostadi, Kyle Jiang, Yuan Gao, Xiaoxian Zhang, Davide Brivio, Paolo Grassini
The effect of compression on the actual structure and transport properties of the carbon cloth gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC) are studied here. Structural features of GDL samples compressed in the 0.0 – 100.0 MPa range are encapsulated using polydimethylsiloxane (PDMS) and by employing X-ray micro-tomography to reconstruct direct digital 3D models. Pore size distribution (PSD) and porosity data are acquired directly from these models while permeability, degree of anisotropy and tortuosity are determined through lattice Boltzmann (LB) numerical modelling. The structural models reveal that structural change proceeds through a three-step process, while PSD data suggests a characteristic peak in the pore diameter of 10-14 microns and a decrease in the mean pore diameter from 33 to 12 microns over the range of tested pressures. A mathematical relationship between compression pressure and permeability is determined based on the Kozeny-Carman equation, revealing a one order of magnitude reduction in through-plane permeability for a two order of magnitude increase in pressure. The results also reveal that the degree of anisotropy peaks in the 0.3 – 10.0 MPa range, suggesting that in-plane permeability can be maximised relative to through-plane permeability within a material-specific range of compression pressures.

History

School

  • Aeronautical, Automotive, Chemical and Materials Engineering

Department

  • Aeronautical and Automotive Engineering

Citation

RAMA, P. ... et al, 2011. A numerical study of structural change and anisotropic permeability in compressed carbon cloth polymer electrolyte fuel cell gas diffusion layers. Fuel Cells, 11 (2), pp.274-285.

Publisher

© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Version

NA (Not Applicable or Unknown)

Publication date

2011

Notes

This article is closed access.

ISSN

1615-6846

Language

en