A simple one-pot preparation of N-allenyl amides, ureas, carbamates and sulfonamides using a DMSO/tBuOK protocol
journal contribution
posted on 2015-03-02, 15:12 authored by Thomas W. Bousfield, Marc KimberMarc KimberA one-pot transformation of amides, ureas, carbamates and sulfonamides into synthetically useful N-allenyl analogues using a tBuOK/DMSO protocol is reported. The procedure is experimentally simple and robust, and provides N-allenyl analogues, commonly used within the literature, in yields comparable to the benchmark two-step approach.
Funding
We gratefully acknowledge financial support from the Department of Chemistry at Loughborough University.
History
School
- Science
Department
- Chemistry
Published in
Tetrahedron LettersVolume
56Issue
2Pages
350 - 352Citation
BOUSFIELD, T.W. and KIMBER, M.C., 2015. A simple one-pot preparation of N-allenyl amides, ureas, carbamates and sulfonamides using a DMSO/tBuOK protocol. Tetrahedron Letters, 56 (2), pp. 350 - 352.Publisher
© Elsevier LtdVersion
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2015Notes
NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 56, issue 2, January 2015, DOI: 10.1016/j.tetlet.2014.11.093.ISSN
0040-4039eISSN
1873-3581Publisher version
Language
- en
