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An impedance model for EIS analysis of nickel metal hydride batteries
journal contribution
posted on 2017-05-18, 13:55 authored by Samuel Cruz-Manzo, Paul S. Greenwood, Rui ChenBased on fundamental electrochemical theory, an impedance model for analysis of electrochemical impedance spectroscopy (EIS) of Nickel-Metal Hydride (NiMH) batteries is presented in this study. The resulting analytical expression is analogous to the impedance response of the Randles electrical circuit used for EIS analysis on NiMH batteries. The impedance model is validated against EIS measurements carried out whilst decreasing the state of charge (SOC) of a NiMH battery pack. The diffusion mechanisms during the discharge of the NiMH battery is modelled through a Warburg element derived from diffusion theory considering reflective boundary conditions. ZView Scribner Associates Inc. software allowed the estimation of electrochemical and diffusion parameters from EIS measurements of the NiMH battery. The effect of diffusion mechanisms on EIS measurements is discussed. The results demonstrate that ion transport is the rate-limiting process during the discharge of the NiMH battery. This EIS-modelling study has provided an insight into the interpretation of battery electrochemical mechanisms represented in the Nyquist plot from EIS. It can assist to further EIS-modelling to study and correlate State of Health (SOH) in NiMH batteries for different applications.
History
School
- Aeronautical, Automotive, Chemical and Materials Engineering
Department
- Aeronautical and Automotive Engineering
Published in
Journal of The Electrochemical SocietyVolume
164Issue
7Pages
A1446 - A1446 (A1453)Citation
CRUZ-MANZO, S., GREENWOOD, P.S. and CHEN, R., 2017. An impedance model for EIS analysis of nickel metal hydride batteries. Journal of The Electrochemical Society, 164 (7), pp. A1446-A1453.Publisher
© The Electrochemical SocietyVersion
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Acceptance date
2017-04-18Publication date
2017-05-06Notes
This paper was accepted for publication in the journal Journal of The Electrochemical Society and the definitive published version is available at http://dx.doi.org/10.1149/2.0431707jesISSN
0013-4651eISSN
1945-7111Publisher version
Language
- en