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An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts

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posted on 10.01.2014, 13:15 by Anthony W. Hill, Mark Elsegood, Marc Kimber
An intermolecular hydroamination of allenamides with arylamines has been achieved under mild Au(I) catalysis conditions delivering allylamino E-enamides stereoselectively and in high yield. The reaction is made possible via a convenient method for conjugated N-acyliminium formation.

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  • Science

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  • Chemistry

Citation

HILL, A.W., ELSEGOOD, M.R.J. and KIMBER, M.C., 2010. An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts. Journal of Organic Chemistry, 75 (15), pp. 5406 - 5409

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© American Chemical Society

Version

AM (Accepted Manuscript)

Publication date

2010

Notes

This article was published in the serial Journal of Organic Chemistry [© American Chemical Society]. The definitive version is available at: http://dx.doi.org/10.1021/jo101035n

ISSN

0022-3263

Language

en

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