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Chemoselective oxidation of sulfides to sulfoxides with urea-hydrogen peroxide complex catalysed by diselenide
journal contribution
posted on 2016-05-26, 11:17 authored by Philip C. Bulman Page, Benjamin BuckleyBenjamin Buckley, Claire Elliott, Yohan Chan, Nicolas Dreyfus, Frank MarkenA highly selective catalytic oxidation system has been developed for the conversion of sulfides to the corresponding sulfoxides using urea–hydrogen peroxide as stoichiometric oxidant in the presence of a catalytic quantity of diphenyl diselenide.
Funding
This investigation has enjoyed the support of Eli Lilly (CASE award to C.E.), Loughborough University, the University of East Anglia, and the ERDF (ISCE-Chem & INTERREG IVa programme 4061). We are indebted to The Royal Society for an Industry Fellowship (to P.C.B.P.), Research Councils UK for a RCUK Fellowship (to B.R.B.), and to the EPSRC Mass Spectrometry Unit, Swansea.
History
School
- Science
Department
- Chemistry
Published in
SYNLETTVolume
27Issue
1Pages
80 - 82 (3)Citation
PAGE, P. ... et al., 2016. Chemoselective oxidation of sulfides to sulfoxides with urea-hydrogen peroxide complex catalysed by diselenide. SYNLETT, DOI: 10.1055/s-0034-1378827.Publisher
© Georg ThiemeVersion
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2016Notes
This item will remain closed access until 13/08/2016.ISSN
0936-5214eISSN
1437-2096Publisher version
Language
- en
