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Chiral counterion strategy in Cu-catalyzed asymmetric allylic oxidation of linear alkenes
journal contribution
posted on 2016-05-23, 10:10 authored by Celia A. Incerti-Pradillos, Daniel Hudson, Andrei MalkovAndrei MalkovApplication of a chiral counter-ion strategy in the Kharasch-Sosnovsky reaction is reported. Copper(I) phosphates obtained from axially chiral, BINOL-derived phosphoric acids were investigated as catalysts in the
enantioselective allylic oxidation of acyclic alkenes. Good yields and high regioselectivity towards branched allylic ester have been achieved. The chiral phosphates investigated exhibited modest enantioselectivities.
History
School
- Science
Department
- Chemistry
Published in
Asymmetric CatalysisVolume
2Issue
1Citation
INCERTI-PRADILLOS, C.A., HUDSON, D. and MALKOV, A.V., 2015. Chiral counterion strategy in Cu-catalyzed asymmetric allylic oxidation of linear alkenes. Asymmetric Catalysis, 2(1): pp. 45-50.Publisher
De Gruyter OpenVersion
- VoR (Version of Record)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 Unported (CC BY-NC-ND 3.0) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/3.0/Publication date
2015-01-25Notes
This is an Open Access Article. It is published by De Guyter Open under the Creative Commons Attribution 3.0 Unported Licence (CC BY). Full details of this licence are available at: http://creativecommons.org/licenses/by/3.0/eISSN
2300-4630Publisher version
Language
- en