Fayemiwo - Eco-Friendly Fabrication of Highly Selective Amide-Based Polymer for CO2 Capture.pdf (1.55 MB)
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Eco-friendly fabrication of highly selective amide-based polymer for CO2 capture

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journal contribution
posted on 12.11.2019, 09:29 authored by Kehinde Fayemiwo, Nutchapon Chiarasumran, Seyed ali NabaviSeyed ali Nabavi, Konstantin Loponov, Vasilije ManovicVasilije Manovic, Brahim BenyahiaBrahim Benyahia, Goran VladisavljevicGoran Vladisavljevic
© 2019 American Chemical Society. Porous polymeric adsorbents for CO2 capture (HCP-MAAMs) were fabricated by copolymerization of methacrylamide (MAAM) and ethylene glycol dimethacrylate using acetonitrile and azobisisobutyronitrile as a porogen and initiator, respectively. The X-ray photoelectron and Fourier transform infrared spectra revealed a high density of amide groups in the polymer matrix of HCP-MAAMs, which enabled high selectivity to CO2. The polymer BET surface area and total pore volume was up to 277 m2 g-1 and 0.91 cm3 g-1, respectively. The highest CO2 uptake at 273 K and 1 bar CO2 pressure was 1.45 mmol g-1, and the heat of adsorption was 27-35 kJ mol-1. The polymer with the lowest cross-linking density exhibited an unprecedented CO2/N2 selectivity of 394 at 273 K. Life cycle assessment revealed a lower environmental impact of HCP-MAAMs compared to molecularly imprinted polymers. HCP-MAAMs are eco-friendly CO2 adsorbents owing to their low regeneration energy, environmentally benign fabrication process, and high selectivity.

History

School

  • Aeronautical, Automotive, Chemical and Materials Engineering

Department

  • Chemical Engineering

Published in

Industrial and Engineering Chemistry Research

Volume

58

Issue

39

Pages

18160 - 18167

Publisher

American Chemical Society

Version

AM (Accepted Manuscript)

Rights holder

© American Chemical Society

Publisher statement

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial and Engineering Chemistry Research, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.iecr.9b02347

Acceptance date

05/09/2019

Publication date

2019-09-05

Copyright date

2019

ISSN

0888-5885

Language

en

Depositor

Dr Goran Vladisavljevic. Deposit date: 11 November 2019