The usual identification of reactive trajectories for the calculation of reaction rates requires very timeconsuming simulations, particularly if the environment presents memory effects. In this paper, we develop a
method that permits the identification of reactive trajectories in a system under the action of a stochastic colored
driving. This method is based on the perturbative computation of the invariant structures that act as separatrices
for reactivity. Furthermore, using this perturbative scheme, we have obtained a formally exact expression for the
reaction rate in multidimensional systems coupled to colored noisy environments.
Funding
The research leading to these results has received funding
from the Ministerio de Economía, Industria y Competitividad,
Gobierno de España under Contract No. MTM2015-63914-
P, from ICMAT Severo Ochoa under Grant No. SEV-2015-
0554, and from the European Union’s Horizon 2020 research
and innovation programme under Grant No. 734557.
History
School
Science
Department
Mathematical Sciences
Published in
Physical Review E
Volume
99
Issue
5
Citation
BARTSCH, T. .... et al., 2019. Finite-barrier corrections for multidimensional barriers in colored noise. Physical Review E, 99: 052211.
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/
Acceptance date
2019-04-22
Publication date
2019-05-15
Notes
This paper was accepted for publication in the journal Physical Review E, and the definitive published version is available at https://doi.org/10.1103/physreve.99.052211