Heterogeneous catalytic reactions "on water" by using stable polymeric alkynylcopper(I) pre-catalysts: alkyne/azide cycloaddition reactions

Buckley, Benjamin; Dann, Sandie; Heaney, Harry; Stubbs, Emma C.

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Heterogeneous catalytic reactions "on water" by using stable polymeric alkynylcopper(I) pre-catalysts: alkyne/azide cycloaddition reactions

journal contribution

posted on 2013-11-18, 15:15 authored by Benjamin BuckleyBenjamin Buckley, Sandie DannSandie Dann, Harry Heaney, Emma C. Stubbs

Dinuclear alkynylcopper(I) complexes have been found to be the active pre-catalysts in copper-catalysed cycloaddition of azides and terminal alkynes (CuAAC). These copper(I) ladderane polymers are used in “on water” CuAAC reactions, with loadings as low as 1 mol-%.

History

School

Science

Department

Chemistry

Citation

BUCKLEY, B.R. ... et al, 2011. Heterogeneous catalytic reactions "on water" by using stable polymeric alkynylcopper(I) pre-catalysts: alkyne/azide cycloaddition reactions. European Journal of Organic Chemistry, 4, pp. 770 - 776.

Publisher

Version

AM (Accepted Manuscript)

Publication date

2011

Notes

This article is closed access, it was published in the serial European Journal of Organic Chemistry [© Wiley-VCH Verlag GmbH]. The definitive version is available at: http://dx.doi.org/10.1002/ejoc.201001326