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Highly sensitive 26Al measurements by Ion-Laser-InterAction Mass Spectrometry

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journal contribution
posted on 26.03.2021, 14:05 by Johannes Lachner, Martin Martschini, Andreas Kalb, Michael Kern, Oscar Marchhart, Felix PlasserFelix Plasser, Alfred Priller, Peter Steier, Alexander Wieser, Robin Golser
The method of Ion-Laser InterAction Mass Spectrometry (ILIAMS) offers new options for the determination of 26Al by Accelerator Mass Spectrometry (AMS) and improves the sensitivity and efficiency for the detection of this isotope in artificial and environmental samples. In ILIAMS, a laser is overlapped with the ion beam during its passage through a radiofrequency quadrupole ion cooler. Those ions with electron affinity lower than the energy of the photons are selectively neutralized in a photodetachment process.

Because the electron affinity of MgO is lower than that of AlO, ILIAMS can suppress the isobar 26Mg by 14 orders of magnitude. No further isobar suppression on the high-energy side of the spectrometer is necessary, so that the more prolific AlO beam can now also be used at facilities with terminal voltages < 5 MV.

At the 3 MV Vienna Environmental Research Accelerator (VERA) routine 26Al AMS measurements assisted by ILIAMS are performed utilizing AlO extracted from the ion source and charge states 2+ and 3+ for the Al ions after the accelerator on the high-energy side of the spectrometer. The most efficient generation of AlO currents (in the range of several μA) is realized when mixing the Al2O3 sample material with Fe powder. Blank materials are measured down to 26Al/27Al ratios of 5⋅10−16. The efficiency relative to the use of Al extraction is improved typically by a factor 3-5 and thus the new method is useful for measurements with highest sensitivity and down to very low 26Al/27Al ratios.

Funding

RADIATE project under the Grant Agreement 824096 from the EU Research and Innovation programme HORIZON 2020.

ILIAMS research activities by ”Investitionsprojekte” of the University of Vienna.

History

School

  • Science

Department

  • Chemistry

Published in

International Journal of Mass Spectrometry

Volume

465

Publisher

Elsevier BV

Version

VoR (Version of Record)

Rights holder

© The Authors

Publisher statement

This is an Open Access Article. It is published by Elsevier under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Acceptance date

08/03/2021

Publication date

2021-03-18

Copyright date

2021

ISSN

1387-3806

Language

en

Depositor

Dr Felix Plasser. Deposit date: 22 March 2021

Article number

116576