In-situ generation of 2-Iodoxybenzoic Acid (IBX) in the presence of Tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes

Page, Philip C. Bulman; Appleby, Louise M.; Buckley, Benjamin; Allin, Steven M.; McKenzie, Michael J.

In-situ generation of 2-Iodoxybenzoic Acid (IBX) in the presence of Tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes

journal contribution

posted on 2007-09-11, 12:03 authored by Philip C. Bulman Page, Louise M. Appleby, Benjamin BuckleyBenjamin Buckley, Steven M. Allin, Michael J. McKenzie

Primary alcohols are oxidized to the corresponding aldehydes by tetraphenylphosphonium monoperoxysulfate (TPPP) in the presence of catalytic 2-iodobenzoic acid. Over-oxidation to carboxylic acids is not observed, in contrast to the use of catalytic 2-iodobenzoic acid with Oxone as reoxidant.

History

School

Science

Department

Chemistry

Citation

PAGE, B.C.P. ... et al, 2007. In-situ generation of 2-Iodoxybenzoic Acid (IBX) in the presence of Tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes. SYNLETT, 2007 (10), pp. 1565-1568

Publisher

Publication date

2007

Notes

This is a Restricted Item. It was published in the journal, SYNLETT [© Georg Thieme Verlag] and is available at http://www.sciencedirect.com/science/journal/00404020