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Interplay between structural, magnetic, and electronic states in the pyrochlore iridate Eu2Ir2O7

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posted on 2022-12-07, 16:38 authored by Manjil Das, Sayantika Bhowal, Jhuma Sannigrahi, Abhisek Bandyopadhyay, Anupam Banerjee, Giannantonio Cibin, Dmitry Khalyavin, Niladri Banerjee, Devashibhai Adroja, Indra Dasgupta, Subham Majumdar

We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions, and density functional theory (DFT)-based calculations. The temperature dependent powder x-ray diffraction clearly rules out any change in the lattice symmetry below the MIT, nevertheless a clear anomaly in the Ir-O-Ir bond angle and Ir-O bond length is evident at the onset of MIT. From the x-ray absorption near edge structure (XANES) spectroscopic study of Ir-L3 and L2 edges, the effective spin-orbit coupling is found to be intermediate, at least quite far from the strong atomic spin-orbit coupling limit. Powder neutron diffraction measurement is in line with an all-in-all-out magnetic structure of the Ir-tetrahedra in this compound, which is quite common among rare-earth pyrochlore iridates. The sharp change in the Ir-O-Ir bond angle around the MIT possibly arises from the exchange striction mechanism, which favors an enhanced electron correlation via weakening of Ir-Ir orbital overlap and an insulating phase below TMI. The theoretical calculations indicate an insulating state for shorter bond angle validating the experimental observation. Our DFT calculations show a possibility of intriguing topological phase below a critical value of the Ir-O distance, which is shorter than the experimentally observed bond length. Therefore, a topological state may be realized in bulk Eu2Ir2O7 sample if the Ir-O bond length can be reduced by the application of sufficient external pressure. 

Funding

Spin-Orbit Coupling-Driven Superconducting Spintronics

Engineering and Physical Sciences Research Council

Find out more...

UKIERI Project [Grant No. DST/INT/UK/P-132/2016]

CSIR, India

SERB-India

TRC (DST)

ETH Zurich

History

School

  • Science

Department

  • Physics

Published in

Physical Review B: Condensed Matter and Materials Physics

Volume

105

Issue

13

Publisher

American Physical Society (APS)

Version

  • VoR (Version of Record)

Rights holder

© American Physical Society

Publisher statement

This paper Manjil Das, Sayantika Bhowal, Jhuma Sannigrahi, Abhisek Bandyopadhyay, Anupam Banerjee, Giannantonio Cibin, Dmitry Khalyavin, Niladri Banerjee, Devashibhai Adroja, Indra Dasgupta, and Subham Majumdar, Phys. Rev. B 105, 134421 was published by American Physical Society (APS) and the definitive published version is available at https://doi.org/10.1103/PhysRevB.105.134421

Acceptance date

2022-04-06

Publication date

2022-04-18

Copyright date

2022

ISSN

1098-0121

eISSN

1550-235X

Language

  • en

Depositor

Dr Niladri Banerjee. Deposit date: 2 December 2022

Article number

134421

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