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Kinetic study of NaBH4 hydrolysis over carbon supported ruthenium

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journal contribution
posted on 20.04.2011, 11:16 authored by Yinghong Shang, Rui Chen, G. Jiang
The effects of temperature and the concentrations of NaBH4, NaBO2 and NaOH on the rate of NaBH4 hydrolysis over carbon supported ruthenium catalyst were investigated using isothermal rate data extracted from non-isothermal reactions. It was shown that the hydrolysis was a zero-order reaction with respect to the concentration of NaBH4 and the reaction rate decreased with the increase of OH- concentration. A rate expression was then derived to correlate the hydrolysis rate with the temperature and NaOH concentration.

History

School

  • Aeronautical, Automotive, Chemical and Materials Engineering

Department

  • Aeronautical and Automotive Engineering

Citation

SHANG, Y., CHEN, R. and JIANG, G., 2008. Kinetic study of NaBH4 hydrolysis over carbon supported ruthenium. International Journal of Hydrogen Energy, 33(22), pp. 6719-6726

Publisher

© Elsevier

Version

AM (Accepted Manuscript)

Publication date

2008

ISSN

0360-3199

Language

en

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