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Mixed-metal calix[8]arene complexes: structure, and ring opening polymerisation studies

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posted on 2022-07-01, 13:12 authored by Tian Xing, Max Derbyshire, Mark ElsegoodMark Elsegood, Carl Redshaw

Reactions of différent combinations of group V alkoxides or tungsten oxyalkoxide salts with p-tert-butylcalix[8]areneH8 (L8H8) affords mixed-metal calix[8]arene systems. Intruiging molecular structures are formed and the systems are capable of the ring opening polymerisation of ε-caprolactone under N2, air, or as melts affording mostly low molecular weight products.

History

School

  • Science

Department

  • Chemistry

Published in

Chemical Communications

Volume

58

Issue

53

Pages

7427 - 7430

Publisher

Royal Society of Chemistry (RSC)

Version

  • VoR (Version of Record)

Rights holder

Journal is © The Royal Society of Chemistry

Publisher statement

This is an Open Access Article. It is published by Royal Society of Chemistry under the Creative Commons Attribution 3.0 Unported Licence (CC BY). Full details of this licence are available at: https://creativecommons.org/licenses/by/3.0/

Acceptance date

2022-06-08

Publication date

2022-06-08

Copyright date

2022

ISSN

1359-7345

eISSN

1364-548X

Language

  • en

Depositor

Dr Mark Elsegood. Deposit date: 10 June 2022

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