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Nanofiltration of organic solvents

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journal contribution
posted on 2009-09-02, 10:19 authored by J.P. Robinson, Steve Tarleton, C.R. Millington, Arian Nijmeijer
Transport mechanisms and process limitations are relatively well understood for aqueous nanofiltration systems. Much work has also been done on the use of membranes for the removal of suspended matter from organic solvents. The removal of organic solute compounds from organic solvents using membrane technology has been addressed by very few workers, and little is known of the fundamental transport and separation mechanisms. The work aims to enhance the understanding of non-aqueous nanofiltration by focusing on the flux performance of organic solvents through a dense 2 μm polydimethylsiloxane composite membrane. The flux of alcohols, n-alkanes, i-alkanes and cyclic compounds were studied in deadend mode, at pressures of 10–900 kPa. Fluxes of 10–80 l/m2 h were obtained for alkanes and cyclic compounds, whereas alcohol flux was around two orders of magnitude lower. The results suggest that the solvent flux through polydimethylsiloxane takes place via two distinct mechanisms – namely hydraulic and chemical transport. Hydraulic transport appears to dominate at pressures above 300 kPa, whereas chemical transport becomes more apparent at lower pressures. Comparison of the hydraulic transport data with a Hagen-Poisuelle model gives good agreement for similar solvents. Swelling effects caused by solvent-membrane interactions are identified as playing a major role in solvent flux behaviour, and compressibility effects are also thought to account for deviations from the Hagen-Poisuelle model. Viscous flow was verified by a nonseparation of mixtures of n-alkane and cyclic compounds, which suggests that the polydimethylsiloxane layer cannot sustain a dense structure when used in organic solvent nanofiltration applications.



  • Aeronautical, Automotive, Chemical and Materials Engineering


  • Chemical Engineering


ROBINSON, J.P. ... et al, 2004. Nanofiltration of organic solvents. Membrane technology, 2004(7), pp. 5-12.


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This article was published in the journal, Membrane technology [© Elsevier] and the definitive version is available at: http://dx.doi.org/10.1016/S0958-2118(04)00180-6. It is based on a paper with the same title which was presented at the 16th American Filtration Society Annual Technical Conference and Exposition.




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