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Oxidative azo-ene cyclization
journal contributionposted on 10.01.2017, 10:58 by Nolwenn Derrien, James S. Sharley, Aleksandr E. Rubtsov, Andrei MalkovAndrei Malkov
An expedient procedure for catalytic oxidative azo–ene cyclization of allylic and homoallylic 1,2-hydrazinedicarboxylates is reported. The reaction produced a wide range of cyclic carbamate derivatives featuring an appended alkene fragment ready for further functionalization.
The authors thank the Russian Science Foundation for Grant 15-13-00092 and Loughborough University for a fellowship to N.D. and other support.