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Oxidative dehomologation of aldehydes with oxygen as a terminal oxidant

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journal contribution
posted on 08.12.2017 by Sergei A. Shipilovskikh, Aleksandr E. Rubtsov, Andrei Malkov
A mild, efficient protocol for oxidative cleavage of C-C bond in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range.

Funding

The authors thank Russian Science Foundation for grant 15-13-00092.

History

School

  • Science

Department

  • Chemistry

Published in

Organic Letters

Volume

19

Issue

24

Pages

6760-6762

Citation

SHIPILOVSKIKH, S.A., RUBTSOV, A.E. and MALKOV, A.V., 2017. Oxidative dehomologation of aldehydes with oxygen as a terminal oxidant. Organic Letters, 19(24), pp. 6760-6762.

Publisher

© American Chemical Society (ACS)

Version

AM (Accepted Manuscript)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Acceptance date

24/11/2017

Publication date

2017-11-28

Copyright date

2017

Notes

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.orglett.7b03512.

ISSN

1523-7052

Language

en

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