Oxidative dehomologation of aldehydes with oxygen as a terminal oxidant
journal contribution
posted on 2017-12-08, 11:01 authored by Sergei A. Shipilovskikh, Aleksandr E. Rubtsov, Andrei MalkovAndrei MalkovA mild, efficient protocol for oxidative cleavage of C-C bond in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range.
Funding
The authors thank Russian Science Foundation for grant 15-13-00092.
History
School
- Science
Department
- Chemistry
Published in
Organic LettersVolume
19Issue
24Pages
6760-6762Citation
SHIPILOVSKIKH, S.A., RUBTSOV, A.E. and MALKOV, A.V., 2017. Oxidative dehomologation of aldehydes with oxygen as a terminal oxidant. Organic Letters, 19(24), pp. 6760-6762.Publisher
© American Chemical Society (ACS)Version
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Acceptance date
2017-11-24Publication date
2017-11-28Copyright date
2017Notes
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.orglett.7b03512.ISSN
1523-7052Publisher version
Language
- en
