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Recent advances in the synthesis of 2,2’-Bipyridines and their derivatives

journal contribution
posted on 15.03.2021, 10:15 by Alexander Rubtsov, Andrei Malkov
The sustained interest in the synthesis of new analogs of 2,2’- bipyridines is supported by the importance of compounds featuring bipyridine core in diverse areas of chemical, biomedical and materials research, which relayed into the development of new and expansion of the existing synthetic methods. This short review covers advances in the synthesis of 2,2’- bipyridines, including both synthesis of compounds with a given substitution pattern and development of new methods for assembling the bipyridine core. Special attention is directed to the use of pyridine-N-oxides, as well as metalfree protocols, to facilitate the formation of bipyridines. The review mostly focus on reports published in the last 5-6 years.
1. Introduction
2. Ullmann-type homocoupling reactions
3. Cross-coupling reactions in the synthesis of bipyridines
4. Coupling reactions employing pyridine-N-oxides
5. Other methods for the synthesis of 2,2’-bipyridines
6. Conclusions and further outlook

Funding

Russian Science Foundation Grant 18-73- 10156

History

School

  • Science

Department

  • Mathematical Sciences

Published in

Synthesis: journal of synthetic organic chemistry

Publisher

Thieme Publishing

Version

AM (Accepted Manuscript)

Publisher statement

This paper was accepted for publication in the journal Synthesis: journal of synthetic organic chemistry and the definitive published version is available at https://doi.org/10.1055/s-0040-1706030

Acceptance date

26/02/2021

Publication date

2021-03-11

ISSN

0039-7881

eISSN

1437-210X

Language

en

Depositor

Prof Andrei Malkov. Deposit date: 11 March 2021

Exports