JECHEM-D-21-00021-accepted manuscript.pdf (1.95 MB)
Download fileS vacancy modulated ZnxCd1−xS/CoP quantum dots for efficient H2 evolution from water splitting under visible light
journal contribution
posted on 2021-04-15, 14:47 authored by Qi Xie, Min Wang, Yong Xu, Xiaoke Li, Xin Zhou, Liang Hong, Luhua Jiang, Wen-Feng LinWen-Feng LinEnergy band structure and interfacial compatibility of heterojunctions are crucial for
photocatalysts in promoting photogenerated charge separation and transfer. Here, a
combined strategy of vacancy engineering and quantum effect via a facile phosphating
process is reported, for the first time, to modulate the energy band structure and the
interface of ZnxCd1-xS/CoP quantum dots (ZCSv/CoP QDs) heterojunction. The
combined experimental and theoretical investigation revealed that phosphating process
transformed CoOx QDs to CoP QDs, and more importantly, generated considerable
amount of sulfur vacancies in ZCSv. As a result, a Type II ZCSv/CoP QDs
heterojunction with compatible interfaces was constructed via in-situ generated P-Zn,
P-Cd and S-Co bonds, which facilitated the separation and transfer of the
photogenerated charge and thus resulted in a high ability towards hydrogen evolution
under visible light. This work provides an effective and adaptable strategy to modulate
band structure and interfacial compatibility of heterojunctions via vacancy engineering
and quantum effect
Funding
Taishan Scholar Program of Shandong Province (ts201712046)
Key Research and Development Programme of Shandong Province (2019JZZY010905)
Natural Science Foundation of Shandong Province (ZR2020QB132)
Liaoning BaiQianWan Talents Program, and the Royal Society and the Newton Fund (NAF\R1\191294)
History
School
- Aeronautical, Automotive, Chemical and Materials Engineering
Department
- Chemical Engineering
Published in
Journal of Energy ChemistryVolume
61Pages
210 - 218Publisher
Elsevier BVVersion
- AM (Accepted Manuscript)
Rights holder
© 2021 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of SciencesPublisher statement
This paper was accepted for publication in the journal Journal of Energy Chemistry and the definitive published version is available at https://doi.org/10.1016/j.jechem.2021.03.019Acceptance date
2021-03-16Publication date
2021-04-08Copyright date
2021ISSN
2095-4956Publisher version
Language
- en