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Solubility and thermodynamics of D-glucosamine 2-sulfate sodium salt in water and binary solvent mixtures with methanol, ethanol and n-propanol

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journal contribution
posted on 18.02.2021, 13:31 by Lijie Wang, Huaiyu YangHuaiyu Yang, Zehao Si, YiZhen Yan, Xiangyang Zhang, Xinggui Zhou
© 2019 Elsevier B.V. Solubility of D-glucosamine 2-sulfate sodium salt in water and binary aqueous mixtures with methanol, ethanol or n-propanol were firstly reported from 288.15 K to 318.15 K under 0.1 MPa. The results showed that the solubility of GS in water is about three orders of magnitude higher than its solubility in alcohols, and the solubility increases with increasing temperature and the composition of the alcohols. Thermodynamic properties of D-glucosamine 2-sulfate sodium salt, such as melting temperature, and decomposition temperature were determined by DSC and TGA. The solubility in various pure and binary solvents was correlated and compared by the modified Apelblat equation, Jouyban-Acree model, Wilson model, and NRTL model. Mixing thermodynamic properties, such as the mixing Gibbs energy, mixing enthalpy, and the mixing entropy of D-glucosamine 2-sulfate sodium salt in these solvents were estimated and analyzed.

Funding

National Natural Science Foundation of China (NSFC, No. 21406071)

Open Project of State Key Laboratory of Chemical Engineering (SKL-ChE-16C03)

History

School

  • Aeronautical, Automotive, Chemical and Materials Engineering

Department

  • Chemical Engineering

Published in

Journal of Molecular Liquids

Volume

300

Publisher

Elsevier

Version

AM (Accepted Manuscript)

Rights holder

© The authors

Publisher statement

This paper was accepted for publication in the journal Journal of Molecular Liquids and the definitive published version is available at https://doi.org/10.1016/j.molliq.2019.112218

Acceptance date

25/11/2019

Publication date

2019-11-28

Copyright date

2020

ISSN

0167-7322

Language

en

Depositor

Dr Huaiyu Yang. Deposit date: 17 February 2021

Article number

112218