Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base

Elsegood, Mark; Kimber, Marc

Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base

journal contribution

posted on 2015-03-02, 15:39 authored by Mark ElsegoodMark Elsegood, Marc KimberMarc Kimber

Pyridyl-assisted templating of phenyl boronic acid has been utilised to link two remote boroxines via a chiral spacer. The chiral spacer is a carbocyclic analogue of Tröger's base and contains a unique chiral cavity, and the flanking boroxine units have been shown, by single crystal X-ray analysis, to extend the size and shape of this cavity.

History

School

Science

Department

Chemistry

Published in

Tetrahedron Letters

Volume

56

Issue

2

Pages

346 - 349

Citation

ELSEGOOD, M.R.J. and KIMBER, M.C., 2015. Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base. Tetrahedron Letters, 56 (2), pp. 346 - 349

Publisher

Version

AM (Accepted Manuscript)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

2015

Notes

NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 56, issue 2, January 2015, DOI:10.1016/j.tetlet.2014.11.094