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The synthesis, full characterisation and utilisation of template-free silica sodalite, a novel polymorph of silica
journal contributionposted on 2014-08-20, 11:05 authored by Roberto S.P. King, Sandie DannSandie Dann, Mark ElsegoodMark Elsegood, Paul KellyPaul Kelly, Roger J. Mortimer
Empty glass: Subjecting ethylene glycol silica sodalite to heat (680 °C) under a nitrogen atmosphere (i) successfully removes the templating agent to give cubic silica sodalite, which, upon consequent heating under an oxygen atmosphere (ii), transforms into a rhombohedral form of the empty sodalite, in effect a novel polymorph of silica.
Funded by EPSRC and Loughborough University
Published inCHEMISTRY-A EUROPEAN JOURNAL
Pages5441 - 5443 (3)
CitationKING, R.S.P., DANN, S.E., ELSEGOOD, M.R.J. ... et al., 2009. The synthesis, full characterisation and utilisation of template-free silica sodalite, a novel polymorph of silica. Chemistry - A European Journal, 15 (22), pp. 5441 - 5443.
Publisher© WILEY-VCH Verlag GmbH & Co
- AM (Accepted Manuscript)
NotesClosed access. This is the accepted version of the following article: King, R. S. P., Dann, S. E., Elsegood, M. R. J., Kelly, P. F. and Mortimer, R. J., 2009. The Synthesis, Full Characterisation and Utilisation of Template-Free Silica Sodalite, a Novel Polymorph of Silica. Chem. Eur. J., 15, pp. 5441–5443, which has been published in final form at http://dx.doi.org/doi: 10.1002/chem.200802551.