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Download fileTowards a total synthesis of the manadomanzamine alkaloids: the first asymmetric construction of the pentacyclic indole core
journal contribution
posted on 26.06.2007, 13:45 authored by Steven Allin, Liam J. Duffy, Philip C. Bulman Page, Vickie McKee, Michael J. McKenzieWe report a highly diastereoselective approach for the synthesis of the pentacyclic indole core of the manadomanzamine alkaloid skeleton, with complete control over the relative and absolute stereochemistries at the three contiguous stereocentres at ring positions 1, 10, and 24, from a readily available chiral template.
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