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Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability
journal contribution
posted on 2015-07-22, 11:56 authored by Jing Ma, Ke-Qing Zhao, Mark J. Walton, Joseph A. Wright, David L. Hughes, Mark ElsegoodMark Elsegood, Kenji Michiue, Xinsen Sun, Carl RedshawA number of vanadyl complexes bearing tri- or tetradentate
phenoxyimine ligands have been structurally
characterized and shown to exhibit high catalytic activity
for ethylene polymerization in the presence of
diethylaluminium chloride and ethyltrichloroacetate; at
high temperatures, such complexes were also capable of
Q4 the ROP of ε-caprolactone.
History
School
- Science
Department
- Chemistry
Published in
DALTON TRANSACTIONSVolume
43Issue
44Pages
16698 - 16706 (9)Citation
MA, J. ... et al, 2014. Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability. Dalton Transactions, 43 (44), pp.16698-16706Publisher
© Royal Society of ChemistryVersion
- NA (Not Applicable or Unknown)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2014Notes
This paper is closed access.ISSN
1477-9226Publisher version
Language
- en
