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Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability

journal contribution
posted on 22.07.2015, 11:56 by Jing Ma, Ke-Qing Zhao, Mark J. Walton, Joseph A. Wright, David L. Hughes, Mark ElsegoodMark Elsegood, Kenji Michiue, Xinsen Sun, Carl Redshaw
A number of vanadyl complexes bearing tri- or tetradentate phenoxyimine ligands have been structurally characterized and shown to exhibit high catalytic activity for ethylene polymerization in the presence of diethylaluminium chloride and ethyltrichloroacetate; at high temperatures, such complexes were also capable of Q4 the ROP of ε-caprolactone.

History

School

  • Science

Department

  • Chemistry

Published in

DALTON TRANSACTIONS

Volume

43

Issue

44

Pages

16698 - 16706 (9)

Citation

MA, J. ... et al, 2014. Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability. Dalton Transactions, 43 (44), pp.16698-16706

Publisher

© Royal Society of Chemistry

Version

NA (Not Applicable or Unknown)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

2014

Notes

This paper is closed access.

ISSN

1477-9226

Language

en

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