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Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability
journal contribution
posted on 2015-07-22, 11:56 authored by Jing Ma, Ke-Qing Zhao, Mark J. Walton, Joseph A. Wright, David L. Hughes, Mark ElsegoodMark Elsegood, Kenji Michiue, Xinsen Sun, Carl RedshawA number of vanadyl complexes bearing tri- or tetradentate
phenoxyimine ligands have been structurally
characterized and shown to exhibit high catalytic activity
for ethylene polymerization in the presence of
diethylaluminium chloride and ethyltrichloroacetate; at
high temperatures, such complexes were also capable of
Q4 the ROP of ε-caprolactone.
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