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Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability
journal contributionposted on 2015-07-22, 11:56 authored by Jing Ma, Ke-Qing Zhao, Mark J. Walton, Joseph A. Wright, David L. Hughes, Mark ElsegoodMark Elsegood, Kenji Michiue, Xinsen Sun, Carl Redshaw
A number of vanadyl complexes bearing tri- or tetradentate phenoxyimine ligands have been structurally characterized and shown to exhibit high catalytic activity for ethylene polymerization in the presence of diethylaluminium chloride and ethyltrichloroacetate; at high temperatures, such complexes were also capable of Q4 the ROP of ε-caprolactone.
Published inDALTON TRANSACTIONS
Pages16698 - 16706 (9)
CitationMA, J. ... et al, 2014. Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability. Dalton Transactions, 43 (44), pp.16698-16706
Publisher© Royal Society of Chemistry
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Publisher statementThis work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/
NotesThis paper is closed access.