Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts

Ekubo, Allen T.; Elsegood, Mark; Lake, Andrew; Smith, Martin

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Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts

journal contribution

posted on 2014-09-26, 14:12 authored by Allen T. Ekubo, Mark ElsegoodMark Elsegood, Andrew Lake, Martin SmithMartin Smith

Rare examples of homodinuclear zwitterionic PdII and PtII complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN- (R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.

History

School

Science

Department

Chemistry

Published in

INORGANIC CHEMISTRY

Volume

49

Issue

8

Pages

3703 - 3705 (3)

Citation

EKUBO, A.T. ... et al, 2010. Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts. Inorganic Chemistry, 49 (8), pp. 3703 - 3705.

Publisher

Version

NA (Not Applicable or Unknown)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

2010

Notes

This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see: http://dx.doi.org/10.1021/ic1002308