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Download fileUnusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts
journal contribution
posted on 2014-09-26, 14:12 authored by Allen T. Ekubo, Mark ElsegoodMark Elsegood, Andrew Lake, Martin SmithMartin SmithRare examples of homodinuclear zwitterionic PdII and PtII complexes
with bridging, two-coordinate P{cyclo-CH2N(R)CHN-
(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been
characterized by single-crystal X-ray diffraction using synchrotron
radiation. Short N-C distances and enlarged N-C-N bond
angles support electron delocalization in the central N-C-N
backbone.
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