Versatile routes to selenoether functionalised tertiary phosphines

Cunningham, Tom J.; Elsegood, Mark; Kelly, Paul; Smith, Martin; Staniland, Paul M.

Dalton Trans Comm Manuscript LUPIN (MBSmith).pdf (125.48 kB)

Versatile routes to selenoether functionalised tertiary phosphines

journal contribution

posted on 30.09.2014, 12:53 by Tom J. Cunningham, Mark ElsegoodMark Elsegood, Paul KellyPaul Kelly, Martin SmithMartin Smith, Paul M. Staniland

New selenoether functionalised tertiary phosphines, based on aryl (2a, 2b) or alkyl (4) backbones, have been synthesised and characterised. P,Se-chelation has been achieved upon complexation to square-planar PtII (3a) or PdII (3b) metal centres. For 3a and 3b, weak non-covalent M◊ ◊ ◊ Se contacts were established using single crystal X-ray crystallography.

History

School

Science

Department

Chemistry

Published in

DALTON TRANSACTIONS

Volume

39

Issue

22

Pages

5216 - 5218 (3)

Citation

CUNNINGHAM, T.J. ... et al, 2010. Versatile routes to selenoether functionalised tertiary phosphines. Dalton Transactions, 39 (22), pp. 5216 - 5218.

Publisher

Version

AM (Accepted Manuscript)

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

2010

Notes

This article was published in the journal, Dalton Transactions [© The Royal Society of Chemistry]. The definitive version is available at: http://dx.doi.org/10.1039/c0dt00004c