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A study of some quinoxaline and halo-pyridine complexes of transition metals

thesis
posted on 09.10.2018 by David E. Billing
The preparations and properties of fifty-three new complexes of Cobalt (II), Nickel (II), Copper (II) and Copper (I) halides and nitrates are described. The ligands used were 3-Bromopyridine, 4-Chloropyridine, 1:2:4-Triazole, Quinoxaline, 2-Methylquinoxaline, 2:3-Dimethylquinoxaline, 2:3-Diphenylquinoxaline and Phenazine. The electronic reflectance spectra of these complexes have been measured, and the spin-allowed transitions assigned. The calculated ligand-field parameters are compared with those of related complexes, and the value of such calculations assessed. The spectra, along with confirmatory magnetic and infrared data are used to elucidate the stereochemistries of the complexes. [Continues.]

Funding

Loughborough University of Technology (research scholarship).

History

School

  • Science

Department

  • Chemistry

Publisher

© D.E. Billing

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1967

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

en

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