Thesis-1999-Aucott.pdf (7.66 MB)
Coordination chemistry of aminophosphine ligands
thesis
posted on 2018-08-14, 10:20 authored by Stephen M. AucottThe reaction of [MCl2(cod)] (M = Pt, Pd) with two equivalents of 2-(diphenylphosphinoamino)pyridine, Ph2PNHpy, in warm acetonitrile led to
cationic complexes of the type cis-[MCl(Ph2PNHpy-P,N){Ph2PNHpy-P}][Cl]
(M = Pt, Pd) which exhibit broad single 31P{1H} NMR resonances due to their
dynamic pyridyl exchange behaviour in solution. A single crystal X-ray
diffraction study of the platinum species confirmed the proposed structure and
revealed that adjacent complex molecules were held together by hydrogen bonding
to the same chloride counter-ion. The bromo- and iodo-cis[MX(Ph2PNHpy-P,N){Ph2PNHpy-P}][X] (M = Pt, Pd; X = Br, I) complexes were obtained by metathesis from the corresponding chloride complex. [Continues.]
Funding
Loughborough University.
History
School
- Science
Department
- Chemistry
Publisher
© Stephen Mark AucottPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1999Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en