Thesis-1991-Jackson.pdf (4.54 MB)
Diels–Alder reactions of heterocyclic fused [alpha]-pyrones
thesisposted on 2017-12-11, 15:09 authored by P. Mark Jackson
The chemistry of heterocyclic analogues of orthoquinodimethane is reviewed. Benzothieno[2,3-c]pyran-3-ones and the isomeric [3,2-c]pyranones are stable analogues of benzothiophene-2,3-qyinodimethane. When heated with alkynes they undergo Diels-Alder reaction to give, after loss of carbon dioxide, dibenzothiophenes. [Continues.]
Science and Engineering Research Council.
Publisher© Mark Jackson
Publisher statementThis work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/
NotesA Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.