Thesis-1971-Cox.pdf (4.34 MB)

Kinetic studies on the two-phase nitration of chlorobenzene and toluene

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posted on 22.11.2018, 16:30 by Philip R. Cox
The rate of nitration of chlorobenzene and toluene by mixed acid has been studied in a small batch reactor. The rate of nitration of chlorobenzene was studied in both homogeneous and two-phase systems. Measurement of the solubility of chlorobenzene in aqueous sulphuric acid enabled an excellent correlation to be obtained between the single- and two-phase rate data. In this way kinetic control of the two-phase reaction rate was demonstrated. An identical system was used to study the rate of nitration of toluene in a chlorobenzene solution. The experimental results showed that under these conditions, the mass transfer and kinetic rates were competing for control of the overall reaction rate. A novel method of plotting the experimental data enabled values of the volumetric mass transfer coefficient and the homogeneous second order rate constant to be obtained. [Continues.]

Funding

Hickson and Welch Ltd (Castleford) (research scholarship).

History

School

  • Science

Department

  • Chemistry

Publisher

© Philip Roger Cox

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1971

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of the degree of Doctor of Philosophy at Loughborough University.

Language

en

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Keywords

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